Enantioselective Aldol Reaction

Organic Synthesis Experimental Activity: Enantioselective Aldol Reaction
Watch the following video from the Second Semester Organic Chemistry Lab at Eastern Kentucky University, U.S.
https://youtu.be/PzLgmB6WJrY

  1. Provide the chemical reaction and mechanism of the enantioselective Aldol reaction being performed in this video.
  2. Explain what the term “enantioselective” means? Does it mean something different from “enantiospecific”?
  3. Which enantiomer is being formed preferentially?
  4. Explain how the reaction is able to be enantioselective?
  5. What is being used in place of an enol or enolate? Explain the reactivity of this nucleophile in comparison to an enol and enolate using resonance contributors of each.
  6. Write out the reaction procedure and fill in the following reaction table.

Sample Solution